[PIPE2D-444] Explanation for broad Argon linees Created: 24/Jul/19  Updated: 08/Aug/19  Resolved: 08/Aug/19

Status: Done
Project: DRP 2-D Pipeline
Component/s: None
Affects Version/s: None
Fix Version/s: None

Type: Task Priority: Normal
Reporter: ncaplar Assignee: ncaplar
Resolution: Done Votes: 0
Labels: None
Remaining Estimate: Not Specified
Time Spent: Not Specified
Original Estimate: Not Specified

Attachments: PDF File 1-s2.0-0031916364906274-main.pdf     PDF File Self-BroadeningIntheRareGases.pdf     PDF File W_R_Hindmarsh_1961_Proc._Phys._Soc._77_313.pdf    
Story Points: 2
Sprint: 2DDRP-2019 F
Reviewers: hassan

 Description   

We now believe that we have isolated the reason that some Argon lines are broad (PIPE2D-439). JEG suggest to use the equations from the paper attached to calculate what pressure would our lamp need to have to explain the observed effect. After we calculate that pressure we could see if the derived value is reasonable to explain what we see.



 Comments   
Comment by ncaplar [ 01/Aug/19 ]

FWHM of the Lorentzian needed to reproduce the broadening is around 0.27 Angstrom (preliminary). To what pressure does that correspond....Uf, Uf... Working on it...

Comment by ncaplar [ 01/Aug/19 ]

Using the values for the ``broadening constant'' from paper ``Pressure broadening and oscillator strengths in Argon'' (attached), measured broadening, and using insights from https://www.semrock.com/measuring-light-with-wavelengths-wavenumbers.aspx to convert weird units I get that number density of Argon in our lamps is 2.5x10**22 atoms in L, i.e., around 0.04 mol in a liter. This is what one would expect if this Argon is under standard conditions (1/22.4 mol in a liter). I think our lamps are under-pressured, but perhaps on a bit different temperature than in the paper... It is roughly in the correct ballpark.

From the same paper, the broadening of the other lines which have the same lower level (but different spin) should be around 4.2 times smaller, i.e., around 0.07 Angstrom.

From the literature, the shifts of the lines should be around 3 to 3.5 times smaller than the broadening, so I would expect a bit less than 0.1 Angstrom shift for the 5 lines that exhibit broadening.

Comment by ncaplar [ 01/Aug/19 ]

Sending email to Jim, if he is happy with this I will close.

Comment by ncaplar [ 08/Aug/19 ]

Jim was a bit suspicious that the values are so close to the standard conditions but given that we do not know the physical properties in the lamp he did not think these values are completly ridiculous. As such, I suggest that we close this ticket. We discussed this issue during DRP2D telecom on Aug 02 - I will summarize the issues raised there in the separate ticket.

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